Roseneath – (Queensland) Chlorate
15/5/19: Roseneath (Qld) Chlorates 940µg/L.
Localised incident as chlorates at all other sites were low. Hypochlorite stock was replaced at Roseneath Reservoir and resamples returned chlorate concentration of at 0.559 µg/L and 0.320µg/L. Readvised staff of the requirement to monitor stock appropriately and replace before stock becomes old and decays, even if it means replacing it before it has been used up.
Chlorite: ADWG Health 0.3mg/L.
Chlorite and chlorate are disinfection by-products of chlorine dioxide disinfection process.
“… industry are having serious problems meeting chlorite/chlorate limits that were proposed in the new Australian Drinking Water Guidelines, especially for disinfection in long distance pipelines that are dosed with sodium hyptochlorite” pers comm 18/5/11.
“Chlorite occurs in drinking water when chlorine dioxide is used for purification purposes. The
International Agency for Research on Cancer (IARC) has concluded that chlorite is not classifiable as carcinogenic to humans and is listed in the Group 3 category. Changes in red blood vessels due to oxidative stress are a major concern with excessive levels of Chlorite in drinking water. According to the US EPA, potential health problems for people drinking Chorite above safe drinking water guideline include: Anemia in infants and young children and nervous system effects.” https://water.epa.gov/drink/contaminants/index.cfm
“Chlorine dioxide (chlorite) is rarely used as a disinfectant in Australian reticulated supplies.
When used, the chlorite residual is generally maintained between 0.2mg/L and 0.4mg/L. It is
particularly effective inthe control of manganese-reducing bacteria. Few data are available on
chlorate levels in Australian water supplies….Chlorine dioxide, chlorite, and chlorate are all
absorbed rapidly by the gastrointestinal tract into blood plasma and distributed to the major
organs. All compounds appear to be rapidly metabolised. Chlorine dioxide has been shown to
impair neurobehavioural and neurological development in rats exposed before birth. Experimental studies with rats and monkeys exposed to chlorine dioxide in drinking water have shown some evidence of thyroid toxicity; however, because of the studies’ limitations, it is difficult to draw firm conclusions (WHO 2005) The primary concern with chlorite and chlorate is oxidative stress resulting in changes in red blood cells. This end point is seen in laboratory animals and, by analogy with chlorate, in humans exposed to high doses in poisoning incidents (WHO 2005).” Australian Drinking Water Guidelines – National Health and Medical Research Centre
“…Subchronic studies in animals (cats, mice, rats and monkeys) indicate that chlorite and chlorate cause haematological changes (osmotic fragility, oxidative stress, increase in mean corpuscular volume), stomach lesions and increased spleen and adrenal weights… Neurobehavioural effects (lowered auditory startle amplitude, decreased brain weight and decreased exploratory activity) are the most sensitive endpoints following oral exposure to chlorite…” https://www.hc-sc.gc.ca/ewh-semt/pubs/water-eau/chlorite-chlorate/indexeng.
php#sec10_1Guidelines for Canadian Drinking Water Quality.