2011/14 – Broome (Western Australia). Silica, pH

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Broome (Western Australia) – Silica

2013/14 Broome (Western Australia) Silica 90mg/L (max), 88mg/L (av)

To minimise an undesirable scale build up on surfaces, silica (SiO2) within drinking waters should not exceed 80 mg/L.
GENERAL DESCRIPTION
Silica present in water is usually referred to as amorphous silica (i.e. lacking any crystalline structure). When silica is dissolved within water it forms monosilicic acid:
SiO2 + 2H2O à Si(OH)4
When the concentrations of monosilicic acid increase, polymerisation of the silica occurs, forming polysilicic acids followed by formation of colloidal silica. Monosilicic acid and polysilicic acids are the forms of silica analysed when determining dissolved silica content.
The deposition of silica from solutions can occur via various mechanisms. The deposition of silica that can cause the most problems for the water industry is via silica’s ability to deposit on solid surfaces that have hydroxyl (OH) groups present. Surfaces that commonly have hydroxyl groups present are glass and metallic surfaces. For example, dissolved silica will react with the surfaces of glass and begin to form a white precipitate. The silica forms silicates on the surface, resulting in silica build-up. In cases where customer complaints occur due to scale build-up, water hardness and silica concentrations should be investigated to determine the cause.
Silica can be a problem in water treatment due to its ability to cause fouling of reverse osmosis (RO) membranes (Sheikholeslami and Tan, 1999, Ning 2002, Sahachaiyunta and Sheikholeslami 2002). This occurs when the dissolved silica of the concentrate becomes super-saturated, causing silicates to form in the presence of metals, and these deposit on the membrane surface. The silicate then dehydrates, forming hard layers on the membrane that reduce the effectiveness of the process… 2011 ADWG

Broome (Western Australia) – pH (acidic)

2011/12 Broome (Western Australia) pH 6.48 (av)

Based on the need to reduce corrosion and encrustation in pipes and fittings, the pH of
drinking water should be between 6.5 and 8.5.

New concrete tanks and cement-mortar lined pipes can significantly increase pH and
a value up to 9.2 may be tolerated, provided monitoring indicates no deterioration in
microbiological quality.

pH is a measure of the hydrogen ion concentration of water. It is measured on a logarithmic scale from 0 to 14. A pH of 7 is neutral, greater than 7 is alkaline, and less than 7 is acidic.

One of the major objectives in controlling pH is to minimise corrosion and encrustation in pipes and fittings. Corrosion can be reduced by the formation of a protective layer of calcium carbonate on the inside of the pipe or fitting, and the formation of this layer is affected by pH, temperature, the availability of calcium (hardness) and carbon dioxide. If the water is too alkaline (above pH 8.5), the rapid deposition and build-up of calcium carbonate that can result may eventually block the pipe.