Wallaville Water Treatment Area Queensland. Trihalomethanes, Chlorine

2013/14: Wallaville – Trihalomethanes

The Burnett River can contain varying elevated levels of natural organics. The current configuration of the Wallaville WTP struggles to deal with the elevated levels and therefore at times the THM levels in the treated water can exceed the ADWG, health value of 250μg/L. Four (4) of eight (8) samples taken over various locations and at varying times within the Wallaville WSA exceeded the ADWG, health value. The average exceedance was around 289μg/L.

Bundaberg Regional Council Drinking Water Quality Annual Report 2013/14

Trihalomethanes Australian Guideline Level 250μg/L (0.25mg/L)

Why and how are THMs formed?
“When chlorine is added to water with organic material, such as algae, river weeds, and decaying leaves, THMs are formed. Residual chlorine molecules react with this harmless organic material to form a group of chlorinated chemical compounds, THMs. They are tasteless and odourless, but harmful and potentially toxic. The quantity of by-products formed is determined by several factors, such as the amount and type of organic material present in water, temperature, pH, chlorine dosage, contact time available for chlorine, and bromide concentration in the water. The organic matter in water mainly consists of a) humic substance, which is the organic portion of soil that remains after prolonged microbial decomposition formed by the decay of leaves, wood, and other vegetable matter; and b) fulvic acid, which is a water soluble substance of low molecular weight that is derived from humus”. US EPA

Wallaville – Chlorine

2022/23: Wallaville Chlorine. Two of three sample points tested above 5.0mg/L, sample/environmental contamination issue, resamples compliant, internal incident 

GENERAL DESCRIPTION
Chlorine dissociates in water to form free chlorine, which consists of aqueous molecular chlorine, hypochlorous acid and hypochlorite ion. Chlorine and hypochlorites are toxic to microorganisms and are used extensively as disinfectants for drinking water supplies. Chlorine is also used to disinfect sewage and wastewater, swimming pool water, in-plant supplies, and industrial cooling water.

Chlorine has an odour threshold in drinking water of about 0.6 mg/L, but some people are particularly sensitive and can detect amounts as low as 0.2 mg/L. Water authorities may need to exceed the odour threshold value of 0.6 mg/L in order to maintain an effective disinfectant residual.

In the food industry, chlorine and hypochlorites are used for general sanitation and for odour control. Large amounts of chlorine are used in the production of industrial and domestic disinfectants and bleaches, and it is used in the synthesis of a large range of chemical compounds.

Free chlorine reacts with ammonia and certain nitrogen compounds to form combined chlorine. With ammonia, chlorine forms chloramines (monochloramine, dichloramine and nitrogen trichloride or trichloramine) (APHA 2012). Chloramines are used for disinfection but are weaker oxidising agents than free chlorine.

Free chlorine and combined chlorine may be present simultaneously (APHA 2012). The term totalchlorine refers to the sum of free chlorine and combined chlorine present in a sample.

Chlorine (Free) ADWG Guideline: 5mg/L (Chlorine in chloraminated supplies 4.1mg/L). Chlorine dissociates in water to form free chlorine, which consists of aqueous molecular chlorine, hypochlorous acid and hypochlorite ion.

Chlorine (Total) ADWG Guideline 5mg/L (chloraminated supplies 4.1mg/L): The term total chlorine refers to the sum of free chlorine and combined chlorine present in a sample

Wallaville (Queensland)  – Lead

2013/2014: Wallaville Lead 0.006mg/L (max), <0.001mg/L (av.)

Lead Guideline reduced from 0.01mg/L to 0.005mg/L in June 2025. “The concentration of lead in water within premises may be higher, especially in older buildings, due to contact of the water with lead-containing plumbing products (enHealth 2021). A review found several Australian and international studies that detected up to 0.162 mg/L of lead in drinking water due to leaching from lead-containing plumbing materials including taps and lead service lines, suggesting that leaching of lead from lead-containing plumbing materials can be substantial (SLR 2023)… Based on health considerations, the concentration of lead in drinking water should not exceed 0.005 mg/L.”

2013/14 + 2022/23 – Wallaville (Queensland) – Trihalomethanes, Chlorine, Lead

Wallaville Water Treatment Area Queensland. Trihalomethanes, Chlorine 2013/14: Wallaville – Trihalomethanes The Burnett River can contain varying elevated levels of natural organics. The current configuration of the Wallaville WTP struggles to deal with the elevated levels and therefore at times the THM levels in the treated water can exceed the ADWG, health value of 250μg/L. Four (4) of eight (8) samples taken over various locations and at varying times within the Wallaville WSA exceeded the ADWG, health value. The average exceedance was around 289μg/L. Bundaberg Regional Council Drinking Water Quality Annual Report 2013/14 Trihalomethanes Australian Guideline Level 250μg/L (0.25mg/L) Why and how are THMs formed? “When chlorine is added to water with organic material, such as algae, river weeds, and decaying leaves, THMs are formed. Residual chlorine molecules react with this harmless organic material to form a group of chlorinated chemical compounds, THMs. They are tasteless and odourless, but harmful and potentially toxic. The quantity of by-products formed is determined by several factors, such as the amount and type of organic material present in water, temperature, pH, chlorine dosage, contact time available for chlorine, and bromide concentration in the water. The organic matter in water mainly consists of a) humic substance, which is the organic portion of soil that remains after prolonged microbial decomposition formed by the decay of leaves, wood, and other vegetable matter; and b) fulvic acid, which is a water soluble substance of low molecular weight that is derived from humus”. US EPA Wallaville – Chlorine 2022/23: Wallaville Chlorine. Two of three sample points tested above 5.0mg/L, sample/environmental contamination issue, resamples compliant, internal incident GENERAL DESCRIPTION Chlorine dissociates in water to form free chlorine, which consists of aqueous molecular chlorine, hypochlorous acid and hypochlorite ion. Chlorine and hypochlorites are toxic to microorganisms and are used extensively as disinfectants for drinking water supplies. Chlorine is also used to disinfect sewage and wastewater, swimming pool water, in-plant supplies, and industrial cooling water. Chlorine has an odour threshold in drinking water of about 0.6 mg/L, but some people are particularly sensitive and can detect amounts as low as 0.2 mg/L. Water authorities may need to exceed the odour threshold value of 0.6 mg/L in order to maintain an effective disinfectant residual. In the food industry, chlorine and hypochlorites are used for general sanitation and for odour control. Large amounts of chlorine are used in the production of industrial and domestic disinfectants and bleaches, and it is used in the synthesis of a large range of chemical compounds. Free chlorine reacts with ammonia and certain nitrogen compounds to form combined chlorine. With ammonia, chlorine forms chloramines (monochloramine, dichloramine and nitrogen trichloride or trichloramine) (APHA 2012). Chloramines are used for disinfection but are weaker oxidising agents than free chlorine. Free chlorine and combined chlorine may be present simultaneously (APHA 2012). The term totalchlorine refers to the sum of free chlorine and combined chlorine present in a sample. Chlorine (Free) ADWG Guideline: 5mg/L (Chlorine in chloraminated supplies 4.1mg/L). Chlorine dissociates in water to form free chlorine, which consists of aqueous molecular chlorine, hypochlorous acid and hypochlorite ion. Chlorine (Total) ADWG Guideline 5mg/L (chloraminated supplies 4.1mg/L): The term total chlorine refers to the sum of free chlorine and combined chlorine present in a sample Wallaville (Queensland)  – Lead 2013/2014: Wallaville Lead 0.006mg/L (max), <0.001mg/L (av.) Lead Guideline reduced from 0.01mg/L to 0.005mg/L in June 2025. “The concentration of lead in water within premises may be higher, especially in older buildings, due to contact of the water with lead-containing plumbing products (enHealth 2021). A review found several Australian and international studies that detected up to 0.162 mg/L of lead in drinking water due to leaching from lead-containing plumbing materials including taps and lead service lines, suggesting that leaching of lead from lead-containing plumbing materials can be substantial (SLR 2023)… Based on health considerations, the concentration of lead in drinking water should not exceed 0.005 mg/L.”