2013/17 – Warra (Queensland) – E.coli, Trihalomethanes, Chlorate, Hardness, Total Dissolved Solids, Chloride, Sodium, Manganese

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2017 May – Warra (Queensland) – E.coli
On the 31st of May 2017 a positive detection of E.coli was recorded from an operational monitoring sample collected from the Warra water tower. The chlorine level at the sample
location at time of sampling was 0.3mg/L.
http://www.wdrc.qld.gov.au/wp-content/uploads/2018/01/DWQMP-Annual-Report-2016-2017.pdf

“Coliforms are Gram-negative, non-spore-forming, rod-shaped bacteria that are capable of aerobic and facultative anaerobic growth in the presence of bile salts or other surface active agents with similar growth-inhibiting properties. They are found in large numbers in the faeces of humans and other warm-blooded animals, but many species also occur in the environment.

Thermotolerant coliforms are a sub-group of coliforms that are able to grow at 44.5 ± 0.2°C. E. coli is the most common thermotolerant coliform present in faeces and is regarded as the most specific indicator of recent faecal contamination because generally it is not capable of growth in the environment. In contrast, some other thermotolerant coliforms (including strains of Klebsiella, Citrobacter and Enterobacter) are able to grow in the environment and their presence is not necessarily related to faecal contamination. While tests for thermotolerant coliforms can be simpler than for E. coli, E. coli is considered a superior indicator for detecting faecal contamination…” ADWG 2011

2013/17 – Warra (Queensland) Trihalomethanes

2016 December: Warra (Queensland) Trihalomethanes ~510μg/L (av 2013/17 ~340μg/L)

Trihalomethanes Australian Guideline Level 250μg/L (0.25mg/L)

Why and how are THMs formed?
“When chlorine is added to water with organic material, such as algae, river weeds, and decaying leaves, THMs are formed. Residual chlorine molecules react with this harmless organic material to form a group of chlorinated chemical compounds, THMs. They are tasteless and odourless, but harmful and potentially toxic. The quantity of by-products formed is determined by several factors, such as the amount and type of organic material present in water, temperature, pH, chlorine dosage, contact time available for chlorine, and bromide concentration in the water. The organic matter in water mainly consists of a) humic substance, which is the organic portion of soil that remains after prolonged microbial decomposition formed by the decay of leaves, wood, and other vegetable matter; and b) fulvic acid, which is a water soluble substance of low molecular weight that is derived from humus”. US EPA

2017 September: Warra (Queensland) – Chlorate ~2mg/L (highest level) – (av 2014/17 ~0.8mg/L)

Each of these plants normally had sufficient stocks of hypochlorite to last about 3 months. At irregular intervals each plant would receive a tanker delivery of about 500 litres. The hypochlorite tanks were generally protected from sunlight but were stored at ambient temperature. Chlorate detections tended to peak in the summer time and be less frequent in cooler months. Hypochlorite solution breaks down with time but at an increased decay rate in higher temperature.
To address this staff developed a procedure where a small quantity of hypochlorite was hauled at frequent intervals to the plants from larger facilities. Warra and Bell are serviced by Jandowae and Condamine from Miles. This helps to ensure that the hypochlorite is regularly refreshed and has a much lower average life. It also assists the larger facility to turn over its s tocks more regularly

http://www.wdrc.qld.gov.au/wp-content/uploads/2017/05/Drinking-Water-Quality-Management-Plan-Annual-Report-2015-2016.pdf

Chlorite: ADWG Health 0.3mg/L.

Chlorite and chlorate are disinfection by-products of chlorine dioxide disinfection process.

“… industry are having serious problems meeting chlorite/chlorate limits that were proposed in the new Australian Drinking Water Guidelines, especially for disinfection in long distance pipelines that are dosed with sodium hyptochlorite” pers comm 18/5/11.

“Chlorite occurs in drinking water when chlorine dioxide is used for purification purposes. The
International Agency for Research on Cancer (IARC) has concluded that chlorite is not classifiable as carcinogenic to humans and is listed in the Group 3 category. Changes in red blood vessels due to oxidative stress are a major concern with excessive levels of Chlorite in drinking water. According to the US EPA, potential health problems for people drinking Chorite above safe drinking water guideline include: Anemia in infants and young children and nervous system effects.” http://water.epa.gov/drink/contaminants/index.cfm

“Chlorine dioxide (chlorite) is rarely used as a disinfectant in Australian reticulated supplies.
When used, the chlorite residual is generally maintained between 0.2mg/L and 0.4mg/L. It is
particularly effective inthe control of manganese-reducing bacteria. Few data are available on
chlorate levels in Australian water supplies….Chlorine dioxide, chlorite, and chlorate are all
absorbed rapidly by the gastrointestinal tract into blood plasma and distributed to the major
organs. All compounds appear to be rapidly metabolised. Chlorine dioxide has been shown to
impair neurobehavioural and neurological development in rats exposed before birth. Experimental studies with rats and monkeys exposed to chlorine dioxide in drinking water have shown some evidence of thyroid toxicity; however, because of the studies’ limitations, it is difficult to draw firm conclusions (WHO 2005) The primary concern with chlorite and chlorate is oxidative stress resulting in changes in red blood cells. This end point is seen in laboratory animals and, by analogy with chlorate, in humans exposed to high doses in poisoning incidents (WHO 2005).” Australian Drinking Water Guidelines – National Health and Medical Research Centre

“…Subchronic studies in animals (cats, mice, rats and monkeys) indicate that chlorite and chlorate cause haematological changes (osmotic fragility, oxidative stress, increase in mean corpuscular volume), stomach lesions and increased spleen and adrenal weights… Neurobehavioural effects (lowered auditory startle amplitude, decreased brain weight and decreased exploratory activity) are the most sensitive endpoints following oral exposure to chlorite…” http://www.hc-sc.gc.ca/ewh-semt/pubs/water-eau/chlorite-chlorate/indexeng.
php#sec10_1Guidelines for Canadian Drinking Water Quality.

Warra – Queensland – Hardness

2015/16: Warra (Queensland) – Hardness 248mg/L (Highest Detection), (234av)

2016/17: Warra (Queensland) – Hardness 438mg/L (Highest Detection), (358.5av)

GUIDELINE

“To minimise undesirable build‑up of scale in hot water systems, total hardness (as calcium
carbonate) in drinking water should not exceed 200 mg/L.

Hard water requires more soap than soft water to obtain a lather. It can also cause scale to form on hot water pipes and fittings. Hardness is caused primarily by the presence of calcium and magnesium ions, although other cations such as strontium, iron, manganese and barium can also contribute.”

Australian Drinking Water Guidelines 2011

2015/16 – Warra (Queensland) – Total Dissolved Solids

2015/16: Warra – Queensland Total Dissolved Solids 630mg/L (high) 577.8mg/L av.
2016/17: Warra – Queensland Total Dissolved Solids 1050mg/L (high) 855.5mg/L av.

GUIDELINE

“No specific health guideline value is provided for total dissolved solids (TDS), as there are no
health effects directly attributable to TDS. However for good palatability total dissolved solids
in drinking water should not exceed 600 mg/L.

2015/16 – Warra (Queensland) – Chloride

2015/16: Warra (Queensland)  Chloride 280mg/L (Highest Level), 254mg/L av.

2016/17: Warra (Queensland)  Chloride 550mg/L (Highest Level), 450mg/L av.

“Chloride is present in natural waters from the dissolution of salt deposits, and contamination from effluent disposal. Sodium chloride is widely used in the production of industrial chemicals such as caustic soda, chlorine, and sodium chlorite and hypochlorite. Potassium chloride is used in the production of fertilisers.

The taste threshold of chloride in water is dependent on the associated cation but is in the range 200–300 mg/L. The chloride content of water can affect corrosion of pipes and fittings. It can also affect the solubility of metal ions.

In surface water, the concentration of chloride is usually less than 100 mg/L and frequently below 10 mg/L. Groundwater can have higher concentrations, particularly if there is salt water intrusion.

Based on aesthetic considerations, the chloride concentration in drinking water should not exceed 250 mg/L.

No health-based guideline value is proposed for chloride.” 2011 Australian Drinking Water Guidelines

2016/17 – Warra – (Queensland) – Sodium

2016/17:  Warra (Queensland)  Sodium 240mg/L (high), 203.67mg/L (average)

“Based on aesthetic considerations (taste), the concentration of sodium in drinking water
should not exceed 180 mg/L….The sodium ion is widespread in water due to the high solubility of sodium salts and the abundance of mineral deposits. Near coastal areas, windborne sea spray can make an important contribution either by fallout onto land surfaces where it can drain to drinking water sources, or from washout by rain. Apart from saline intrusion and natural contamination, water treatment chemicals, domestic water softeners and
sewage effluent can contribute to the sodium content of drinking water.” ADWG 2011

Warra (Queensland) – Manganese

2016/17: Warra (Queensland) – Manganese 0.69mg/L

Manganese: ADWG Guidelines 0.5mg/L. ADWG Aesthetic Guideline 0.1mg/L
Manganese is found in the natural environment. Manganese in drinking water above 0.1mg/L can give water an unpleasant taste and stain plumbing fixtures and laundry.