2015/16 – Forsayth (Queensland) – Aluminium, Chlorate, Bromide, Colour, Turbidity, Iron

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Forsayth (Queensland) – Aluminium

2015/16: Forsayth (Queensland) Aluminium 4.980mg/L (Highest Level Only), av. 0.526mg/L
Australian Guideline: Aluminium 0.2mg/L

According to the ADWG, no health guideline has been adopted for Aluminium, but that the issue is still open to review. Aluminium can come from natural geological sources or from the use of aluminium salts as coagulants in water treatment plants. According to the ADWG “A well-operated water filtration plant (even using aluminium as a flocculant) can achieve aluminium concentrations in the finished water of less than 0.1 mg/L.

The most common form of aluminium in water treatment plants is Aluminium Sulfate (Alum). Alum can be supplied as a bulk liquid or in granular form. It is used at water treatment plants as a coagulant to remove turbidity, microorganisms, organic matter and inorganic chemicals. If water is particularly dirty an Alum dose of as high as 500mg/L could occur. There is also concern that other metals may also exist in refined alum.

While the ADWG mentions that there is considerable evidence that Aluminium is neurotoxic and can pass the gut barrier to accumulate in the blood, leading to a condition called encephalopathy (dialysis dementia) and that Aluminium has been associated with Parkinsonism dementia and amyotrophic lateral sclerosis, the NHMRC, whilst also acknowledging studies which have linked Aluminium with Alzheimer disease, has not granted Aluminium a NOEL (No Observable Effect Level) due to insufficient and contradictory data. Without a NOEL, a health guideline cannot be established. The NHMRC has also stated that if new information comes to hand, a health guideline may be established in the future.

In communication with Aluminium expert Dr Chris Exley (Professor in Bioinorganic Chemistry
The Birchall Centre, Lennard-Jones Laboratories, Keele University, Staffordshire UK) in March 2013 regarding high levels of Aluminium detected in the South Western Victorian town of Hamilton
“It is my opinion that any value above 0.5 mg/L is totally unacceptable and a potential health risk. Where such values are maintained over days, weeks or even months, as indeed is indicated by the data you sent to me, these represent a significant health risk to all consumers. While consumers may not experience any short term health effects the result of longer term exposure to elevated levels of aluminium in potable waters may be a significant increase in the body burden of aluminium in these individuals. This artificially increased body burden will not return to ‘normal’ levels when the Al content of the potable water returns to normal but will act as a new platform level from which the Al body burden will continue to increase with age.

2015/16: Forsayth (Queensland) – Chlorate

“… We have an ongoing incident for detection of Chlorate – a parameter with no water quality criteria taken from the Forsayth Library. 1.45, 3.13, 19.5, 8.04 & 1.59 Mg/L was/were detected. We are testing for chlorate quarterly and monitoring the situation. We turn over our chlorine as frequent as possible and keep it out of the sun. We are working towards upgrading our treatment plant”

Etheridge Shire Annual Drinking Water Quality Management Plan 2015/16

Chlorite: ADWG Health 0.3mg/L.

Chlorite and chlorate are disinfection by-products of chlorine dioxide disinfection process.

“… industry are having serious problems meeting chlorite/chlorate limits that were proposed in the new Australian Drinking Water Guidelines, especially for disinfection in long distance pipelines that are dosed with sodium hyptochlorite” pers comm 18/5/11.

“Chlorite occurs in drinking water when chlorine dioxide is used for purification purposes. The
International Agency for Research on Cancer (IARC) has concluded that chlorite is not classifiable as carcinogenic to humans and is listed in the Group 3 category. Changes in red blood vessels due to oxidative stress are a major concern with excessive levels of Chlorite in drinking water. According to the US EPA, potential health problems for people drinking Chorite above safe drinking water guideline include: Anemia in infants and young children and nervous system effects.” http://water.epa.gov/drink/contaminants/index.cfm

“Chlorine dioxide (chlorite) is rarely used as a disinfectant in Australian reticulated supplies.
When used, the chlorite residual is generally maintained between 0.2mg/L and 0.4mg/L. It is
particularly effective inthe control of manganese-reducing bacteria. Few data are available on
chlorate levels in Australian water supplies….Chlorine dioxide, chlorite, and chlorate are all
absorbed rapidly by the gastrointestinal tract into blood plasma and distributed to the major
organs. All compounds appear to be rapidly metabolised. Chlorine dioxide has been shown to
impair neurobehavioural and neurological development in rats exposed before birth. Experimental studies with rats and monkeys exposed to chlorine dioxide in drinking water have shown some evidence of thyroid toxicity; however, because of the studies’ limitations, it is difficult to draw firm conclusions (WHO 2005) The primary concern with chlorite and chlorate is oxidative stress resulting in changes in red blood cells. This end point is seen in laboratory animals and, by analogy with chlorate, in humans exposed to high doses in poisoning incidents (WHO 2005).” Australian Drinking Water Guidelines – National Health and Medical Research Centre

“…Subchronic studies in animals (cats, mice, rats and monkeys) indicate that chlorite and chlorate cause haematological changes (osmotic fragility, oxidative stress, increase in mean corpuscular volume), stomach lesions and increased spleen and adrenal weights… Neurobehavioural effects (lowered auditory startle amplitude, decreased brain weight and decreased exploratory activity) are the most sensitive endpoints following oral exposure to chlorite…” http://www.hc-sc.gc.ca/ewh-semt/pubs/water-eau/chlorite-chlorate/indexeng.
php#sec10_1Guidelines for Canadian Drinking Water Quality.

2015/16: Forsayth (Queensland) – Bromide

We have an ongoing incident for detection of Bromide – a parameter with no water quality criteria taken from the Forsayth Library. 0.009 Mg/L was/were detected. Corrective and Preventative Actions We are testing monthly at this stage and monitoring the situation. We turn over our chlorine as frequent as possible and keep it out of the sun.

Etheridge Shire Annual Drinking Water Quality Management Plan 2015/16

Bromide can be involved in the reaction between chlorine and naturally occurring
organic matter in drinking-water, forming brominated and mixed chloro-bromo by-
products, such as trihalomethanes or halogenated acetic acids, or it can react with
ozone to form bromate. The levels of bromide that can result in the formation of these
substances are well below the health-based values suggested above. This guidance
applies specifically to inorganic bromide ion and not to bromate or organohalogen
compounds, for which individual health-based guideline values have been developed.

2015/16 – Forsayth (Queensland) – Colour

2015/16: Forsayth – Colour 22 (highest level)

Based on aesthetic considerations, true colour in drinking water should not exceed 15 HU.

“… Colour is generally related to organic content, and while colour derived from natural sources such as humic and fulvic acids is not a health consideration, chlorination of such water can produce a variety of chlorinated organic compounds as by-products (see Section 6.3.2 on disinfection by-products). If the colour is high at the time of disinfection, then the water should be checked for disinfection by-products. It should be noted, however, that low colour at the time of disinfection does not necessarily mean that the concentration of disinfection by-products will be low…

2016/17 – Forsayth – Turbidity

2016/17: Forsayth – Turbidity 9.9NTU (max)

Chlorine-resistant pathogen reduction: Where filtration alone is used as the water treatment
process to address identified risks from Cryptosporidium and Giardia, it is essential
that filtration is optimised and consequently the target for the turbidity of water leaving
individual filters should be less than 0.2 NTU, and should not exceed 0.5 NTU at any time
Disinfection: A turbidity of less than 1 NTU is desirable at the time of disinfection with
chlorine unless a higher value can be validated in a specific context.

Aesthetic: Based on aesthetic considerations, the turbidity should not exceed 5 NTU at the
consumer’s tap

2015/16 Forsayth (Queensland) – Iron

2015/16: Forsayth (Queensland)  – Iron 0.437mg/L (max)

Based on aesthetic considerations (precipitation of iron from solution and taste),
the concentration of iron in drinking water should not exceed 0.3 mg/L.
No health-based guideline value has been set for iron.

Iron has a taste threshold of about 0.3 mg/L in water, and becomes objectionable above 3 mg/L. High iron concentrations give water an undesirable rust-brown appearance and can cause staining of laundry and plumbing fittings, fouling of ion-exchange softeners, and blockages in irrigation systems. Growths of iron bacteria, which concentrate iron, may cause taste and odour problems and lead to pipe restrictions, blockages and corrosion. ADWG 2011