2005/17 – Laanecoorie (Victoria) – E.coli, Anabaena Circinalis, Lead, Trihalomethanes, Hardness, Total Dissolved Solids, Sodium, Chloride, Turbidity, Manganese

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Laanecoorie (Victoria) – Anabaena circinalis

9/3/07: Laanecoorie Anabaena circinalis count is at 5830 cells/mL
Increase general surveillance and PAC dosing commenced. Increased BGA testing until clear.

Due to the lack of adequate data, no guideline value is set for concentrations of saxitoxins.
However given the known toxicity, the relevant health authority should be notified
immediately if blooms of Anabaena circinalis (Dolichospermum circinalis)1 or other producers
of saxitoxins are detected in sources of drinking water.
GENERAL DESCRIPTION
There are three types of cyanobacterial neurotoxins: anatoxin a, anatoxin a-s and the saxitoxins. The saxitoxins include saxitoxin, neosaxitoxin, C-toxins and gonyautoxins (Chorus and Bartram 1999 Chapter 3). The anatoxins seem unique to cyanobacteria, while saxitoxins are also produced by various dinoflagellates under the name of paralytic shellfish poisons (PSPs). A number of cyanobacterial genera can produce neurotoxins, including Anabaena (Dolichospermum), Oscillatoria, Cylindrospermopsis, Cylindrospermum, Lyngbya and Aphanizomenon, but to date in Australia, neurotoxin production has only been detected from Anabaena circinalis (Dolichospermum circinalis), and the Australian isolates appear to
produce only saxitoxins (Velzeboer et al. 1998). As with most toxic cyanobacteria, A. circinalis (D. circinalis) tends to proliferate in calm, stable waters, particularly in summer when thermal stratification reduces mixing. The toxicity of individual populations of A. circinalis (D. circinalis) is variable, and one extensive survey of the toxicity across the Murray-Darling Basin indicated that 54% of field samples tested were neurotoxic (Baker and Humpage, 1994). A natural population may consist of a mixture of toxic and non-toxic strains and this is believed to explain why population toxicity may vary over time and between samples (Chorus and Bartram 1999 Chapter 3). The saxitoxins are a group of carbamoyl and decarbamoyl alkaloids that are either non-sulfated (saxitoxins), singly-sulfated (gonyautoxins), or doubly-sulfated (C-toxins). The various types of toxins vary in potency, with saxitoxin having the highest toxicity. The prevalent toxins in Australian blooms of A. circinalis are the C-toxins. These can convert in the environment or by acidification or boiling to more potent toxins (Negri et al. 1997, Ravn et al. 1995). The half-lives for breakdown of a range of different saxitoxins in natural water have been shown to vary from 9 to 28 days, and gonyautoxins may persist in the environment for more than three months (Jones and Negri, 1997).

AUSTRALIAN SIGNIFICANCE
Blooms of A. circinalis (D. circinalis) have been recorded in many rivers, lakes, reservoirs and dams throughout Australia, and A. circinalis (D. circinalis) is the most common organism in riverine blooms in the Murray-Darling Basin (Baker and Humpage 1994). In temperate parts of Australia blooms typically occur from late spring to early autumn. The first reported neurotoxic bloom of A. circinalis (D. circinalis) in Australia occurred in 1972 (May and McBarron 1973). The most publicised blooms occurred in the Murray-Darling System in 1991, 2009 and 2010 (NSWBGATF 1992, NSW Office of Water 2009, MDBA 2010). The first bloom extended over 1,000 kilometres of the Darling-Barwon River system in New South Wales (NSWBGATF 1992). A state of emergency was declared, with a focus on providing safe drinking water to towns, communities and landholders. Stock deaths were associated with the occurrence of the bloom but there was little evidence of human health impacts. The blooms in 2009 and 2010
affected several hundred kilometres of the River Murray on the border between NSW and Victoria and included Anabaena, Microcystis and Cylindrospermopsin. Alerts were issued about risks to recreational use, primary contact by domestic users, livestock and domestic animals. A bloom of A. circinalis (D. circinalis) in a dam in New South Wales was shown to have caused sheep deaths (Negri et al. 1995). Relatively low numbers of A. circinalis (D. circinalis) (below 2,000 cells/mL) can produce offensive tastes and odours in drinking water due to the production of odorous compounds such as geosmin… ADWG 2011

Laanecoorie (Victoria) – E.coli

18/4/07: Laanecoorie (Victoria) 2org/100mL. (sample at customer tap)
No known cause. All possible bird entry points checked. Chlorine residuals checked and seem OK. Re-sampling completed showing no further E.Coli.
“E.coli

Thermotolerant coliforms are a sub-group of coliforms that are able to grow at 44.5 ± 0.2°C. E. coli is the most common thermotolerant coliform present in faeces and is regarded as the most specific indicator of recent faecal contamination because generally it is not capable of growth in the environment. In contrast, some other thermotolerant coliforms (including strains of Klebsiella, Citrobacter and Enterobacter) are able to grow in the environment and their presence is not necessarily related to faecal contamination. While tests for thermotolerant coliforms can be simpler than for E. coli, E. coli is considered a superior indicator for detecting faecal contamination…” ADWG

Laanecoorie  (Victoria) Lead

2011/12 Laanecoorie Lead 0.08mg/L

Lead Australian Drinking Water Guideline 0.01mg/L

“… Lead can be present in drinking water as a result of dissolution from natural sources, or from household plumbing systems containing lead. These may include lead in pipes, or in solder used to seal joints. The amount of lead dissolved will depend on a number of factors including pH, water hardness and the standing time of the water.

Lead is the most common of the heavy metals and is mined widely throughout the world. It is used in the production of lead acid batteries, solder, alloys, cable sheathing, paint pigments, rust inhibitors, ammunition, glazes and plastic stabilisers. The organo-lead compounds tetramethyl and tetraethyl lead are used extensively as anti-knock and lubricating compounds in gasoline…ADWG 2011

Laanecoorie (Victoria) – Trihalomethanes

19/2/16 Laanecoorie THM  0.3mg/L

Trihalomethanes Australian Guideline Level 250μg/L (0.25mg/L)

Why and how are THMs formed?
“When chlorine is added to water with organic material, such as algae, river weeds, and decaying leaves, THMs are formed. Residual chlorine molecules react with this harmless organic material to form a group of chlorinated chemical compounds, THMs. They are tasteless and odourless, but harmful and potentially toxic. The quantity of by-products formed is determined by several factors, such as the amount and type of organic material present in water, temperature, pH, chlorine dosage, contact time available for chlorine, and bromide concentration in the water. The organic matter in water mainly consists of a) humic substance, which is the organic portion of soil that remains after prolonged microbial decomposition formed by the decay of leaves, wood, and other vegetable matter; and b) fulvic acid, which is a water soluble substance of low molecular weight that is derived from humus”. US EPA

Laanecoorie – Victoria – Hardness (max levels only)

2005/06: Laanecoorie (Victoria) – Hardness 360mg/L

2006/07: Laanecoorie (Victoria) – Hardness 490mg/L

2007/8 Laanecoorie Hardness 580mg/L

2008/9 Laanecoorie Hardness 490mg/L

2009/10 Laanecoorie Hardness 540mg/L

2010/11 Laanecoorie Hardness 270mg/L

2015/16 Laanecoorie Hardness 230mg/L

2016/17: Laanecoorie (Victoria) – Calcium Carbonate 320mg/L

GUIDELINE

“To minimise undesirable build‑up of scale in hot water systems, total hardness (as calcium
carbonate) in drinking water should not exceed 200 mg/L.

Hard water requires more soap than soft water to obtain a lather. It can also cause scale to form on hot water pipes and fittings. Hardness is caused primarily by the presence of calcium and magnesium ions, although other cations such as strontium, iron, manganese and barium can also contribute.”

Australian Drinking Water Guidelines 2011

Laanecoorie – Victoria – Total Dissolved Solids (max levels)

2005/06: Laanecoorie (Victoria) – Total Dissolved Solids 1600 μS/cm (max)

2006/07: Laanecoorie (Victoria) – Total Dissolved Solids 2400 μS/cm (max)

2007/8 Laanecoorie Total Dissolved Solids 2700mg/L

2008/9 Laanecoorie Total Dissolved Solids 2300mg/L

2009/10 Laanecoorie Total Dissolved Solids 3000mg/L

2010/11 Laanecoorie Total Dissolved Solids 1700mg/L

2011/12 Laanecoorie Total Dissolved Solids 1400mg/L

2016/17: Laanecoorie (Victoria) – Total Dissolved Solids 1600 μS/cm

GUIDELINE

“No specific health guideline value is provided for total dissolved solids (TDS), as there are no
health effects directly attributable to TDS. However for good palatability total dissolved solids
in drinking water should not exceed 600 mg/L.

Total dissolved solids (TDS) consist of inorganic salts and small amounts of organic matter that are dissolved in water. Clay particles, colloidal iron and manganese oxides and silica, fine enough to pass through a 0.45 micron filter membrane can also contribute to total dissolved solids.

Total dissolved solids comprise: sodium, potassium, calcium, magnesium, chloride, sulfate, bicarbonate, carbonate, silica, organic matter, fluoride, iron, manganese, nitrate, nitrite and phosphates…” Australian Drinking Water Guidelines 2011

Laanecoorie (Victoria) – Sodium

2007/8 Laanecoorie Sodium 280mg/L

2008/9 Laanecoorie Sodium 240mg/L

2009/10 Laanecoorie Sodium 290mg/L

2016/17:  Laanecoorie (Victoria)  Sodium 180mg/L

“Based on aesthetic considerations (taste), the concentration of sodium in drinking water
should not exceed 180 mg/L….The sodium ion is widespread in water due to the high solubility of sodium salts and the abundance of mineral deposits. Near coastal areas, windborne sea spray can make an important contribution either by fallout onto land surfaces where it can drain to drinking water sources, or from washout by rain. Apart from saline intrusion and natural contamination, water treatment chemicals, domestic water softeners and
sewage effluent can contribute to the sodium content of drinking water.” ADWG 2011

Laanecoorie (Victoria) – Chloride

2007/8 Laanecoorie Chloride 570mg/L

2008/9 Laanecoorie Chloride 570mg/L

2009/10 Laanecoorie Chloride 740mg/L

2010/11 Laanecoorie Chloride 330mg/L

2016/17: Laanecoorie (Victoria)  Chloride 400mg/L

“Chloride is present in natural waters from the dissolution of salt deposits, and contamination from effluent disposal. Sodium chloride is widely used in the production of industrial chemicals such as caustic soda, chlorine, and sodium chlorite and hypochlorite. Potassium chloride is used in the production of fertilisers.

The taste threshold of chloride in water is dependent on the associated cation but is in the range 200–300 mg/L. The chloride content of water can affect corrosion of pipes and fittings. It can also affect the solubility of metal ions.

In surface water, the concentration of chloride is usually less than 100 mg/L and frequently below 10 mg/L. Groundwater can have higher concentrations, particularly if there is salt water intrusion.

Based on aesthetic considerations, the chloride concentration in drinking water should not exceed 250 mg/L.

No health-based guideline value is proposed for chloride.” 2011 Australian Drinking Water Guidelines

Laanecoorie –  Victoria – Iron

2007/8 Laanecoorie Iron 0.47mg/L

2008/9 Laanecoorie Iron 0.34mg/L

2011/12 Laanecoorie Iron 3.9mg/L

Based on aesthetic considerations (precipitation of iron from solution and taste),
the concentration of iron in drinking water should not exceed 0.3 mg/L.
No health-based guideline value has been set for iron.

Iron has a taste threshold of about 0.3 mg/L in water, and becomes objectionable above 3 mg/L. High iron concentrations give water an undesirable rust-brown appearance and can cause staining of laundry and plumbing fittings, fouling of ion-exchange softeners, and blockages in irrigation systems. Growths of iron bacteria, which concentrate iron, may cause taste and odour problems and lead to pipe restrictions, blockages and corrosion. ADWG 2011

2009/12 – Laanecoorie (Victoria) – Turbidity

2009/10 Laanecoorie Turbidity 9.2 NTU

2011/12 Laanecoorie Turbidity 6.5 NTU

Chlorine-resistant pathogen reduction: Where filtration alone is used as the water treatment
process to address identified risks from Cryptosporidium and Giardia, it is essential
that filtration is optimised and consequently the target for the turbidity of water leaving
individual filters should be less than 0.2 NTU, and should not exceed 0.5 NTU at any time
Disinfection: A turbidity of less than 1 NTU is desirable at the time of disinfection with
chlorine unless a higher value can be validated in a specific context.

Aesthetic: Based on aesthetic considerations, the turbidity should not exceed 5 NTU at the
consumer’s tap

2011/12 – Laanecoorie (Victoria) – Manganese

2011/12 Laanecoorie Manganese 0.54mg/L

Manganese: ADWG Guidelines 0.5mg/L. ADWG Aesthetic Guideline 0.1mg/L
Manganese is found in the natural environment. Manganese in drinking water above 0.1mg/L can give water an unpleasant taste and stain plumbing fixtures