Linville (Queensland) – Haloacetic Acids
2014/15 Linville: Max Result Dichloroacetic Acid 50 ug/L, Trichloroacetic Acid 74ug/L
In 2016 the Queensland Government set a guideline for combined HAA’s for 100ug/L (0.1mg/L
Australian Guidelines Trichloroacetic Acid 0.100mg/L, Dichloroacetic Acid 0.100mg/L
“Chloroacetic acids are produced in drinking water as by-products of the reaction between chlorine and naturally occurring humic and fulvic acids. Concentrations reported overseas range up to 0.16mg/L and are typically about half the chloroform concentration. The chloroacetic acids are used commercially as reagents or intermediates in the preparation of a wide variety of chemicals. Monochloroacetic acid can be used as a pre-emergent herbicide, dichloroacetic acid as an ingredient in some pharmaceutical products, and trichloroacetic acid as a herbicide, soil sterilant and antiseptic.” Australian Drinking Water Guidelines – National Health and Medical Research Council…
2017/18 – Linville (Queensland) – Trihalomethanes
2017/18: Linville (Queensland) 300μg/l (max)
Trihalomethanes Australian Guideline Level 250μg/L (0.25mg/L)
Why and how are THMs formed?
“When chlorine is added to water with organic material, such as algae, river weeds, and decaying leaves, THMs are formed. Residual chlorine molecules react with this harmless organic material to form a group of chlorinated chemical compounds, THMs. They are tasteless and odourless, but harmful and potentially toxic. The quantity of by-products formed is determined by several factors, such as the amount and type of organic material present in water, temperature, pH, chlorine dosage, contact time available for chlorine, and bromide concentration in the water. The organic matter in water mainly consists of a) humic substance, which is the organic portion of soil that remains after prolonged microbial decomposition formed by the decay of leaves, wood, and other vegetable matter; and b) fulvic acid, which is a water soluble substance of low molecular weight that is derived from humus”. Source: https://water.epa.gov/drink/contaminants/in
2013/14 – Linville (Queensland) – Chlorine
2013/14 – Linville (Queensland) – Chlorine (Total) 5.6mg/L (max)
GENERAL DESCRIPTION
Chlorine dissociates in water to form free chlorine, which consists of aqueous molecular chlorine, hypochlorous acid and hypochlorite ion. Chlorine and hypochlorites are toxic to microorganisms and are used extensively as disinfectants for drinking water supplies. Chlorine is also used to disinfect sewage and wastewater, swimming pool water, in-plant supplies, and industrial cooling water.
Chlorine has an odour threshold in drinking water of about 0.6 mg/L, but some people are particularly sensitive and can detect amounts as low as 0.2 mg/L. Water authorities may need to exceed the odour threshold value of 0.6 mg/L in order to maintain an effective disinfectant residual.
In the food industry, chlorine and hypochlorites are used for general sanitation and for odour control. Large amounts of chlorine are used in the production of industrial and domestic disinfectants and bleaches, and it is used in the synthesis of a large range of chemical compounds.
Free chlorine reacts with ammonia and certain nitrogen compounds to form combined chlorine. With ammonia, chlorine forms chloramines (monochloramine, dichloramine and nitrogen trichloride or trichloramine) (APHA 2012). Chloramines are used for disinfection but are weaker oxidising agents than free chlorine.
Free chlorine and combined chlorine may be present simultaneously (APHA 2012). The term totalchlorine refers to the sum of free chlorine and combined chlorine present in a sample.
Chlorine (Free) ADWG Guideline: 5mg/L (Chlorine in chloraminated supplies 4.1mg/L). Chlorine dissociates in water to form free chlorine, which consists of aqueous molecular chlorine, hypochlorous acid and hypochlorite ion.
Chlorine (Total) ADWG Guideline 5mg/L (chloraminated supplies 4.1mg/L): The term total chlorine refers to the sum of free chlorine and combined chlorine present in a sample
Linville – Queensland – Temperature
2016/17: Linville (Queensland) – Mean Temperature 23C
GUIDELINE
“No guideline is set due to the impracticality of controlling water temperature.
Drinking water temperatures above 20°C may result in an increase in the number of
complaints.
Temperature is primarily an aesthetic criterion for drinking water. Generally, cool water is more palatable than warm or cold water. In general, consumers will react to a change in water temperature. Complaints are most frequent when the temperature suddenly increases.
The turbidity and colour of filtered water may be indirectly affected by temperature, as low water temperatures tend to decrease the efficiency of water treatment processes by, for instance, affecting floc formation rates and sedimentation efficiency.
Chemical reaction rates increase with temperature, and this can lead to greater corrosion of pipes and fittings in closed systems. Scale formation in hard waters will also be greater at higher temperatures…
Water temperatures in major Australian reticulated supplies range from 10°C to 30°C. In some long, above-ground pipelines, water temperatures up to 45°C may be experienced…
The effectiveness of chlorine as a disinfectant is influenced by the temperature of the water being dosed. Generally higher temperatures result in more effective disinfection at a particular chlorine dose, but this may be counterbalanced by a more rapid loss of chlorine to the atmosphere (AWWA 1990).